The composition of the anhydrous ammonia is closely controlled to prevent attack on the pipeline. Astm b858 062018 standard test method for ammonia vapor. Ammonia at high temperature has high potential for nitriding metals. Electrochemistry of stress corrosion cracking of brass m. Stress corrosion cracking in brass is usually localised and, if ammonia has been involved, may be accompanied by black staining of the surrounding surface. Effect of anhydrous ammonia composition on its ability to cause.
Introduction the following article is a followup to industry study indicates stress corrosion cracking in anhydrous ammonia storage vessels, which appeared in the october 1988 bulletin. The stress corrosion cracks are found mainly in the welds, and the attack is dependent upon the type of steel, the impurities in the ammonia, and the stresses in the. The intent is to provide the corrosion engineer with the information needed to make informed decisions in individual applications. The combined effect of water and oxygen on stress corrosion cracking of carbonmanganese steel in liquid and gaseous ammonia has been studied in detail. The main issue is the cryogenic toughness of stainless steels at around 40 degc, compared to carbon steels, which can also be considered for ammonia service under these conditions. Carbon and lowalloy steels scc can occur in other materials stainless steel. This new second edition serves as a goto reference on the complex subject of stress corrosion cracking scc, offering information to help metallurgists, materials scientists, and designers determine whether scc will be an issue for their design or application. This may result in a catastrophic failure of bulk storage vessels. Typically the indication of a leak due to stress corrosion cracking is a strong smell of ammonia gas seeping through a short hairline crack on a pressure vessel. Introduction it is well known that the stress corrosion cracking scc mechanism is caused by the combination of tensile stress and a corrosive medium. Oxygen levels of more than a few ppm in liquid ammonia or a few thousand ppm in gaseous ammonia can promote stress corrosion cracking in steels. First, the part must be stressed, either from an applied force or due to residual stress usually from forming. Again, corrosion alone in the absence of stress does not produce cracking. Anhydrous ammonia is one of the medium where the steel is easy to suffer stress corrosion cracking.
Stress corrosion cracking of carbon steel storage tanks for anhydrous ammonia. Electrochemistry of stress corrosion cracking of brass. Department of transportation regulations provide effective safeguards to prevent this problem through the required use of postweld heat treatment and the use of 0. A study was made to determine relevant growth data and to determine methods to prevent cracking. This cracking can also occur when ammonia is intentionally added to process streams as a neutralizer by someone unaware of its potential effect on brass tubes. This is largely inhibited, however, if the ammonia contains 0. The vessel can be isolated and taken out of service without any risk of catastrophic failure, but of course the economic consequences for the enduser. Further progress is then a process alternating between corrosion. Citeseerx stress corrosion crack tests of 16mnr low. Stress corrosion cracking the international institute of. Stress corrosion cracking in ammonia did not occur in steel specimens with fatigue precracks, due to a crevice corrosion attack. A compressive stress does not cause stress corrosion cracking.
Stress corrosion cracking in refrigeration systems request pdf. Mercury stress corrosion cracking of brass components can also occur in service due to contamination from broken thermometers. Stress corrosion cracking, residual stress, ammonia transporting pipeline 1. The stress level at which the failure occurs is well below the stress required for a mechanical failure in the absence of corrosion. It is generally understood that stress corrosion cracking can occasionally affect the high pressure vessels in ammonia refrigeration systems, but the nature of the problem is often misrepresented in design codes, safety standards and textbooks and ways in which the initiation of stress corrosion can be prevented are ignored. Generally, scc provokes 1 cracks and fractures with a sudden structure rupture 24. Many metals suffer from stress corrosion cracking under certain conditions. Also tanks for transporting liquid ammonia, like rail tank cars.
Predicted growth of throughthickness stress corrosion. Stress corrosion cracking of steel in liquefied ammonia. Stress corrosion tests have been performed on pressure vessel. Jul, 2017 season cracking occurs in copperbased alloys subjected to a residual or applied tensile stress and exposed to a specific environment, such as moist air containing traces of ammonia. Zinc, copper and brass are some materials that should not be brought into contact with ammonia that contains water because ammonia corrosion can occur. Corrosion and stresscorrosion cracking scc tests were performed on aluminum drillpipe alloy 2014t6 in a waterbased, lowsolids, nondispersed lsnd drilling mud. Stress corrosion cracking of astm a517 steel in liquid. This recapitulation of experiences with stresscorrosion cracking of steel in liquefied ammonia summarizes the subject over the last three decades. Predicted growth of throughthickness stress corrosion cracks.
As the result of the studies the research committee recommended 2 that. Evaluation of stress corrosion cracking damage to an api 5l. Carbon steel in anhydrous ammonia can suffer from scc stress corrosion cracking. The growth of stress corrosion cracks increased with stress intensity factor and decreased with exposure time.
Ammonia and stainless steel, corrosion blacksmith37 materials dec 11 15. Scc stress corrosion cracking leaflet product stewardship. The stress corrosion cracking scc behavior of electricresistancewelded erw api grades x42, x46, x52, and x60 linepipe in liquid ammonia has been evaluated for the base metal, erw weldments, and girth weldments. Ammonia corrosion can cause stress corrosion cracking in steels. Cracking has been detected in ammonia storage tanks, spheres and other process equipment that is in contact with liquid ammonia. However, stress corrosion cracking continues to be a problem in aging plants and must be considered when completing risk based inspection rbi. Jul 11, 2011 the committee determined that the failures were most likely caused by stress corrosion cracking and that the probability of cracking increased as the yield strength of the steel increased. Anhydrous ammonia is a toxic material that is transported from distribution centers to farm fields in steel pressure vessels called nurse tanks. According to the american society for metals metals handbook, desk edition, 4 intergranular fracture in carbon steel in the presence of a caustic material, such as anhydrous ammonia, is typical of stresscorrosion cracking. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. Ammonium hydroxide stainless steela ahow good resistance to all concentrations of ammonia. The committee determined that the failures were most likely caused by stresscorrosion cracking and that the probability of cracking increased as the yield strength of the steel increased. Stress corrosion cracking sco of carbon and alloy steels in liquid ammonia has occurred spasmodically over the last twenty years.
The majority of such accidents are caused by stress corrosion cracking of the tank steel. Generally, scc provokes cracks and fractures with a sudden structure rupture 2 4. While it is rare, formed parts can develop fractures after they are placed in service. Pressure vessels should be either fully stress relieved or fabricated with heads that are hotformed or stress relieved. The following article is a followup to industry study indicates stress corrosion cracking in anhydrous ammonia storage vessels, which appeared in the october 1988 bulletin. Season cracking is also known as stress corrosion cracking or environmental cracking. Stress corrosion cracking of carbon steel storage tanks for. This may result in ammonia weeping from a crack within the refrigeration system. It is well known that the stress corrosion cracking scc mechanism is caused by the combination of tensile stress and a corrosive medium 1. Stress corrosion cracking of steel in liquefied ammonia service a. The mechanism of stress corrosion cracking scc involves a very complicated sequence of corrosion and fracture. The formation of cupric complex ions leads to stress corrosion cracking of brass in ammonia solutions. A stateoftheart report on stress corrosion cracking scc of carbon and low alloy steels in anhydrous ammonia service.
The cracks are small at the surface but can be deep, worstcase going through the entire thickness of the metal. Stress corrosion cracking has been detected in ammonia storage tanks, spheres and other process equipment that is in contact with liquid ammonia. Stress corrosion cracking of linepipe steels in anhydrous. It is typically considered resistant to ammonia stress corrosion cracking. Numerous accidents have occurred in which nurse tanks failed and ammonia was released, often with explosive force. Ammonia stress corrosion cracking is a form of stress corrosion cracking that commonly occurs in brass tubes in cooling water service that has been contaminated with ammonia due to biological growths or other contamination. The process does not proceeds indefinitely since the attack of cupric complex ion oxide layer occurs at critical copper ion content which leads to decrease in corrosion rate but the cracking continues with the copper ion concentration. Stainless steels in ammonia production nickel institute. Stresscorrosion cracking occurs in a susceptible material when it is exposed to sustained tensile stresses and a specific environment. Corrosion selection of materials health and safety. Stress corrosion cracking international institute of. Stress corrosion cracking issues in syngas plants that may be.
This type of failure is known as stress corrosion cracking, often abbreviated to scc. His letter indicates that the tampa pipeline corporations plan to inhibit stress corrosion cracking in the pipeline amounts to. Stress corrosion cracking scc of the welds in carbon steel transport and storage tanks for anhydrous ammonia has been experienced worldwide for the last 30 years. At high pressure, corrosive ammonium carbamate may be formed. Carbon steel, alloy steel, and highstrength, quenched and tempered steel, when under applied or residual stress and especially when cold formed andor welded without subsequent thermal stress relief, are subject to failure by stresscorrosion cracking scc in aircontaminated dry ammonia. Care must be taken to ensure that pressure vessels are not subjected to this type of corrosion. This occurs when contaminants in the ammonia are brought into contact with the steel, a situation that commonly occurs with pressure vessels. Generally, scc provokes cracks and fractures with a.
Water in ammonia to protect against stress corrosion. Citeseerx stress corrosion crack tests of 16mnr low alloy. Extreme care should be used to eliminate air from the ammonia systems. The following article is a followup to industry study indicates stress corrosion cracking in anhydrous ammonia storage vessels, which appeared in the. This type of failure is referred to as stress corrosion cracking scc. Water in ammonia to protect against stress corrosion cracking. Corrosion resistance and cryogenic toughness of stainless steels. It can happen at atmospheric liquid ammonia conditions at 33 c, but also at higher temperatures under pressurized ammonia conditions. Anhydrous ammonia in carbon steels and quenchedandtempered lowalloy steels in the presence of air in addition to stress, oxygen is a critical ingredient to enable scc nitrogen aggravates the process source. Season cracking occurs in copperbased alloys subjected to a residual or applied tensile stress and exposed to a specific environment, such as moist air containing traces of ammonia. Further progress is then a process alternating between corrosion and mechanical cracking until the material fails completely. Measures for reducing scc in anhydrous ammonia storage.
The highest susceptibility to scc was found in liquid ammonia with 310 ppm oxygen and a water content lower than 100 ppm. Stress corrosion cracking of brass in ammonia ukessays. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. Measures for reducing scc in anhydrous ammonia storage tanks. Evaluation of stress corrosion cracking damage to an api. Effect of anhydrous ammonia composition on its ability to.
It is generally understood that stress corrosion cracking can occasionally affect the high pressure vessels in ammonia refrigeration systems, but the nature of the problem is often misrepresented in design codes, safety standards and textbooks and ways in which the initiation of. Stresscorrosion cracks in heat affected zone of astm a 202. Predicted growth of throughthickness stress corrosion cracks in. Water can be added to the ammonia to help prevent stress corrosion cracking. Citeseerx document details isaac councill, lee giles, pradeep teregowda. Even trace quantities of chlorides can cause problems at temperatures above 60c.
Condensed ammonia is a corrodent, and in anhydrous state it can cause stresscorrosion cracking of stressed carbon steels or highstrength, lowalloy steels. In piping the most frequent failures from stress corrosion cracking occur with austenitic stainless steels in contact with solutions containing chloride. Ammonia that is mixed with water is not corrosive to iron or steel. Prevention of stress corrosion cracking of carbon steels in. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment.
Stresscorrosion cracking of steels in ammonia with. It is important to realize that not all corrosive environments promote the formation of stress corrosion cracks. Generally, scc provokes 1 cracks and fractures with a. Stress corrosion crack growth of carbon steel in ammonia was studied with compact tension specimens. This recapitulation of experiences with stress corrosion cracking of steel in liquefied ammonia summarizes the subject over the last three decades. The austenitic stainless steels are impact tough at cryogenic temperatures.
Electrochemistry of stress corrosion cracking of brass by. It is generally understood that stress corrosion cracking can occasionally affect the high pressure vessels in ammonia refrigeration systems, but the nature of the problem is often misrepresented. Anhydrous ammonia an overview sciencedirect topics. Variables examined included chloride concentration, temperature, state of aeration, and effects of galvanic coupling to tooljoint steel. I dont remember any ss except the reformer furnace tubesmanifolds hk40 hp mod. Four factors, are required before stress corrosion cracking can occur. Ammonia stress corrosion cracking a mmonia stress corrosion cracking scc is the phenomena of cracks being formed in carbon steel in contact with ammonia. Astm b858062018, standard test method for ammonia vapor test for determining susceptibility to stress corrosion cracking in copper alloys, astm international, west conshohocken, pa, 2018, back to top. Blaine, wa 98230 abstract during the past decade, there has been evidence of stress.
Stress corrosion cracking, residual stress, ammonia transporting pipeline. The wol specimens were not effective in predicting stress corrosion cracking in the liquid ammonia environment. Stress corrosion cracking of carbon steel storage tanks. Many stress corrosion crack accidents of ammonia storage tanks have been reported all over the world for recent years. It has been shown that, for some materials, fine pitting is needed to start the activity. The specificity of environments that will promote stress corrosion cracking is significant. Stress corrosion cracking in refrigeration systems. Selection of stainless steels for handling ammonia nh3. Prevention of stress corrosion cracking of carbon steels.
Ammonia is not corrosive for stainless steel without presence of water or condensate. Impurities in ammonia, such as air or carbon dioxide, can cause stress corrosion cracking. Carbon steel, alloy steel, and highstrength, quenched and tempered steel, when under applied or residual stress and especially when cold formed andor welded without subsequent thermal stress relief, are subject to failure by stress corrosion cracking scc in aircontaminated dry ammonia. Stress corrosion cracking issues in syngas plants that may. Anhydrous ammonia stress corrosion cracking scc incident.
1159 39 1465 302 261 367 699 1068 1369 677 1062 1084 1413 32 613 596 674 987 1488 97 593 562 1283 1248 1435 858 422 867 610 396 807 357 1305 1502 396 797 911 1423 465 1178 1115 946 1280 676 726 170